Volume 603
Main Index

Issue 1, Pages 1-133 (22 May 2000)

Foreword Page 1 Richard D. Adams, Jean-Pierre Genêt

Microwave-mediated palladium-catalyzed asymmetric allylic alkylation; an example of highly selective fast chemistry Pages 2-5 Nils-Fredrik K. Kaiser, Ulf Bremberg, Mats Larhed, Christina Moberg*, Anders Hallberg*

Lanthanide-catalyzed asymmetric 1,3-dipolar cycloaddition of nitrones to alkenes using 3,3′-bis(2-oxazolyl)-1,1′-bi-2-naphthol (BINOL-Box) ligands Pages 6-12 Hidehiko Kodama, Junji Ito, Kazushige Hori, Tetsuo Ohta, Isao Furukawa

A rigid dirhodium(II) carboxylate as an efficient catalyst for the asymmetric cyclopropanation of olefins Pages 13-17 Sophie K. Bertilsson, Pher G. Andersson

Asymmetric aldol reaction of 2-cyanopropionates catalyzed by a trans-chelating chiral diphosphine–rhodium(I) complex: highly enantioselective construction of quaternary chiral carbon centers at α-positions of nitriles Pages 18-29 Ryoichi Kuwano, Hiroshi Miyazaki, Yoshihiko Ito*

Recent progress in asymmetric heterogeneous catalysis: use of polymer-supported catalysts Pages 30-39 Christine Saluzzo, Rob ter Halle, François Touchard, Fabienne Fache, Emmanuelle Schulz, Marc Lemaire

Palladium-catalyzed asymmetric intermolecular arylation of cyclic or acyclic alkenes using phosphinite-oxazoline ligands derived from -glucosamine Pages 40-49 Koji Yonehara, Kenji Mori, Tomohiro Hashizume, Kang-Go Chung, Kouichi Ohe *, Sakae Uemura *

Oxidation of olefins by palladium(II): Part 17. An asymmetric chlorohydrin synthesis catalyzed by a bimetallic palladium(II) complex Pages 50-60 Arab El-Qisairi, Patrick M. Henry

Cooperative attractive interactions in asymmetric hydrogenations with dihydroxydiphosphine Rh(I) catalysts — a competition study Pages 61-68 Jens Holz, Renat Kadyrov*, Susanne Borns, Detlef Heller, Armin Börner*

Chiral molybdenum(VI) and tungsten(VI) 2′-pyridinyl alcoholate complexes. Synthesis, structure and catalytic properties in asymmetric olefin epoxidation Pages 69-79 Wolfgang A. Herrmann, Joachim J. Haider, Jörg Fridgen, Gerhard M. Lobmaier, Michael Spiegler

Aqueous enantioselective hydrogenations involving silica-heterogenised catalysts Pages 80-85 Jim Jamis, John R. Anderson, Ron S. Dickson, Eva M. Campi, W. Roy Jackson

Direct ortho-palladation of 2-phenyl-2-oxazoline: Crystal structure of Cl2Pd(---Ph)2 and Cl(PPh3)Pd(---C6H4) Pages 86-97 Irina P. Smoliakova, Kristopher J. Keuseman, Dana C. Haagenson, Dawn M. Wellmann, Peter B. Colligan, Nadezhda A. Kataeva, Andrey V. Churakov, Lyudmila G. Kuz'mina, Valery V. Dunina

Catalytic applications of F8BINOL: asymmetric oxidation of sulfides to sulfoxides Pages 98-104 L. James P. Martyn, Subramanian Pandiaraju, Andrei K. Yudin

Kinetic resolution in Pd-catalyzed allylic substitution using the helical PHelix ligand Pages 105-109 Manfred T. Reetz, Stefan Sostmann

The application of Pd-complexes of diphenylphosphinoferrocenyloxazoline ligands to catalytic enantioselective allylic amination Pages 110-115 Yvonne M. Malone, Patrick J. Guiry

A new asymmetric synthesis of optically active allenes via metal catalyzed hydrosilylation Pages 116-121 Annegret Tillack, Cornelia Koy, Dirk Michalik, Christine Fischer

Enantioface discriminating carbonylations of styrene with cationic palladium(II) catalyst precursors Pages 122-127 Anton Aeby, Achim Gsponer, Martin Sperrle, Giambattista Consiglio

Asymmetric synthesis of fluorinated β-hydroxy esters via ruthenium-mediated hydrogenation Pages 128-130 D. Blanc, V. Ratovelomanana-Vidal, J. -P. Gillet, J. -P. Genêt

Index Page 133

Issue 2, Pages 135-263 (29 May 2000)

Synthesis and molecular structure of [Fe3(μ2-H)(μ3-Te)(CO)9][Cp#2Nb(CO)2] (Cp#=C5Me5, C5Me4Et) Pages 135-137 Henri Brunner, Joachim Wachter, Robert Wanninger, Manfred Zabel

Competition between sp3 and sp2 C---H bonds in cyclopalladation of N-methyl-α-tert-butylbenzylamine Pages 138-151 Valery V. Dunina, Ol’ga N. Gorunova, Elena B. Averina, Yuri K. Grishin, Lyudmila G. Kuz’mina, Judith A. K. Howard

Synthesis and properties of arylpalladium(II) azido complexes PdAr(N3)(PR3)2. Nucleophilic reactions of the azido ligand with CO and with isocyanides to afford Pd(II) isocyanate, C-tetrazolate and carbodiimide complexes Pages 152-160 Yong-Joo Kim, Yong-Su Kwak, Soon-W. Lee

Bridged aminotroponiminate complexes of lutetium Pages 161-166 Peter W. Roesky

Synthesis and properties of unsolvated bis(cyclopentadienyl)titanium alumohydride. Structure of {[(η5-C5H5)2Ti(μ-H)]2[(η5-C5H5)Ti(μ-H2]Al3(μ-H4)(H)}2·C6H6 a 12-nuclear titanium aluminum hydride complex with a short Al---Al bond length, and refined structure of LiAlEt4 Pages 167-173 A. I. Sizov, T. M. Zvukova, B. M. Bulychev, V. K. Belsky

New palladium complexes with rigid scorpion-type ligands. Crystal structure of complexes [Pd(η3-2-CH3---C3H4)(bpz*mPh)](CF3SO3) and [Pd(bpz*mpy)2](BF4)2. bpz*mPh=phenyl-bis(3,5-dimethylpyrazol-1-yl)methane; bpz*mpy=pyridin-2-yl-bis(3,5-dimethylpyrazol-1-yl)methane Pages 174-184 Nieves Arroyo, Felipe Gómez-de la Torre, Félix A. Jalón, Blanca R. Manzano, B. Moreno-Lara, Ana M. Rodríguez

The first structurally characterised oligosilylmagnesium compound Pages 185-188 James D. Farwell, Michael F. Lappert*, Christoph Marschner*, Christine Strissel, T. Don Tilley*

Nickel-catalyzed allylation of lithium 1-alkynyl(trialkoxy)borates with 1,3-disubstituted allyl carbonates Pages 189-193 Han Chen, Min-Zhi Deng

Studies on the reactivity of alkoxo-niobium(V) compounds towards O,O- or S,S-enolate ligands. Synthesis and structural characterisation of (alkoxo)(β-diketonato)- and (alkoxo)[dialkyl(aryl)dithiocarbamato] complexes of niobium(V) Pages 194-202 A. Antiñolo, F. Carrillo-Hermosilla, J. Fernández-Baeza, S. García-Yuste, A. Otero, E. Palomares, A. M. Rodriguez, L. F. Sánchez-Barba

Preparation, crystal structure determination and properties of adducts of indium methylene compounds with Group 15 donors Pages 203-212 L. de Araújo Felix, C. A. F. de Oliveira, R. K. Kross, C. Peppe, M. A. Brown, D. G. Tuck, M. Z. Hernandes, E. Longo, F. R. Sensato

Synthesis and characterization of organozirconium complexes bearing a new trianionic multidentate cyclopentadienyl ligand by use of amine elimination Pages 213-219 P. Doufou, K. A. Abboud, J. M. Boncella

Synthesis of acylsilanes via oxidative hydrolysis of 2-silyl-1,3-dithianes mediated by N-bromosuccinimide Pages 220-224 Amauri F. Patrocínio, Paulo J. S. Moran

Manganese (I) complexes of p-xylene and [2n] cyclophanes from a theoretical sight Pages 225-234 Roberto Salcedo, Luis E. Sansores, Ana Martínez, Larissa Alexandrova, Montserrat García

Synthesis and resolution of a new P-chiral hydroxy phosphine Pages 235-239 Joan Albert, J. Magali Cadena, Sergio Delgado, Jaume Granell

Reaction of (1-azabuta-1,3-diene)tricarbonyliron(0) complexes with sodium borohydride under microwave conditions Pages 240-243 Joseph Akisanya, Timothy N. Danks, Russell N. Garman

Coordination of a Ru(II)-complex to a tetrafunctional P-ligand: a model for Ru---P carbosilane dendrimers Pages 244-248 Herlinde I. Beerens, Peter Wijkens, Johann T. B. H. Jastrzebski, Francis Verpoort, Ludo Verdonck, Gerard van Koten

Stereoselective preparation of (Z)-α-stannyl-1-alkenyl sulfoxides via hydrozirconation of acetylenic stannanes Pages 249-251 Xian Huang, Ping Zhong, Meng-Ping Guo

Aldol-type condensation reactions of cyclic ketones by the W(CO)6/CCl4/UV system Pages 252-255 Ç. Bozkurt

Index Page 258

Index Pages 259-263